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Using a variety of steady state and time-resolved microscopies, this work directly compares the excited state dynamics of two distinct morphologies of a hierarchical perylene diimide material: a kinetically trapped 1D mesoscale aggregate produced with a redox-assisted self-assembly process, and a thin film produced via conventional solution-processing techniques. Although the constituent monomer is identical for both materials, linear dichroism studies indicate that the kinetically trapped structures possess significantly higher long-range order than the conventional thin film. A comparison of the two systems with broadband pump–probe microscopy reveals distinct differences in their excited state dynamics. In the kinetically trapped structures, polarization-resolved kinetics, as well as a picosecond redshift of the ground state bleach provide evidence for rapid excited state delocalization, which is absent in the thin film. A comparison of transient spectra collected at 1 μs indicates the presence of long-lived charge separated states in redox treated samples, but not in the thin film. These results provide direct evidence that control of the supramolecular assembly process can be leveraged to affect the long-range order of derived PDI materials, thus enabling increased yield and lifetime of charge separated states for light harvesting applications. Furthermore, these results highlight the need for microscale broadband probes of organic materials to accurately capture the influence of local morphology on excited state functionality. 

Structural and functional heterogeneity is a consequence of the weak noncovalent interactions that direct the formation of organic materials from solution precursors. While covalent tethering of solution-phase assemblies provides a compelling strategy to enhance intermolecular order, the effects of this tethering strategy on the formed solid-state materials remain unestablished. This work uses pump–probe microscopy to compare excited-state dynamics in thin films fabricated from tethered perylene bisimide assemblies to those fabricated from noncovalent assemblies. On average, tethered films exhibit faster and more homogeneous excited-state lifetimes, consistent with stronger and more uniform intermolecular coupling. Optical measurements of excited-state diffusion show that the tethered film has ∼75% faster transport than the control film. Kinetic Monte Carlo modeling suggests that the reduction of site energetic disorder is sufficient to quantitatively explain the difference in diffusion coefficients. These results provide strong support that covalent tethering is a promising strategy to enhance the structural and energetic ordering in molecular materials. 

A two-component stapling strategy is used to covalently tether a new class of water-soluble supramolecular polymers built from bay-functionalized perylene bisimide (PBI) units. 

In this work, a NIR emitting dye, p-toluenesulfonate (IR-813) was explored as a model precursor to develop red emissive carbon dots (813-CD) with solvatochromic behavior with a red-shift observed with increasing solvent polarity. The 813-CDs produced had emission peaks at 610 and 698 nm, respectively, in water with blue shifts of emission as solvent polarity decreased. Subsequently, 813-CD was synthesized with increasing nitrogen content with polyethyleneimine (PEI) to elucidate the change in band gap energy. With increased nitrogen content, the CDs produced emissions as far as 776 nm. Additionally, a CD nanocomposite polyvinylpyrrolidone (PVP) film was synthesized to assess the phenomenon of solid-state fluorescence. Furthermore, the CDs were found to have electrochemical properties to be used as an additive doping agent for PVP film coatings.